环氧树脂涂层表面亲水性对微藻黏附性能的影响

在固体材料表面黏附成膜是微藻细胞的一种生理特性。近些年基于微藻生物膜的生物过程，如生物膜贴壁培养和防附着技术受到了很多关注。微藻在固体材料表面的黏附受藻细胞与材料表面之间的相互作用的影响，建立黏附强度与材料表面性质参数间的关系对于通过材料选择来强化或控制微藻生物膜具有非常重要的意义。本工作的目的是揭示和明确材料亲疏水性对微藻黏附的影响，提出了一种双酚A环氧(EP)树脂表面亲疏水改性的方法。通过将亲水性的二乙醇胺(DEA)或疏水性的聚甲基聚硅氧烷(PMHS)加入到EP树脂中反应，EP树脂表面水接触角在36.80?~98.34?范围内可通过加入不同量的DEA或PMHS实现任意可调，材料的表面水接触角与DEA或PMHS加入量之间有线性关系。重要的是这种改性方法获得的材料，其形貌、结构、表面粗糙度等表面性质几乎没有变化，从而在研究和关联微藻黏附量与材料表面亲疏水性(表面水接触角)之间的关系时可以排除亲疏水性之外的其他表面性质的影响；其次，考察了小球藻和栅藻在不同亲疏水性材料表面的黏附行为，结果表明小球藻和栅藻在亲水性和疏水性材料表面均能黏附成膜，但在亲水性材料表面黏附更多更快；建立了微藻最大黏附容量与材料表面接触角之间关联关系，表明微藻最大黏附容量随材料表面水接触角的增大而线性降低，栅藻的表面黏附容量比小球藻大。     

Crystal anisotropy-dependent shear angle variation in orthogonal cutting of single crystalline copper

Shear deformation that dominates elementary chip formation in metal cutting greatly relies on crystal anisotropy. In the present work we investigate the influence of crystallographic orientation on shear angle in ultra-precision orthogonal diamond cutting of single crystalline copper by joint crystal plasticity finite element simulations and in-situ experiments integrated in scanning electron microscope. In particular, the experimental cutting conditions including a straight cutting edge are the same with that used in the 2D finite element simulations. Both simulations and experiments demonstrate a well agreement in chip profile and shear angle, as well as their dependence on crystallography. A series of finite element simulations of orthogonal cutting along different cutting directions for a specific crystallographic orientation are further performed, and predicated values of shear angle are used to calibrate an extended analytical model of shear angle based on the Ernst–Merchant relationship.     

氯化镧对镁合金表面疏水化处理的影响

研究了氯化镧对镁合金疏水膜耐蚀性的影响。采用中性盐雾试验和电化学试验测试了疏水膜的耐蚀性,并采用扫描电子显微镜观察了疏水膜的表面形貌。结果表明:氯化镧对镁合金疏水膜有一定的改性作用,使膜层由乳突状结构转变为层片状结构,进而使膜层由疏水表面转变为超疏水表面,其接触角可达153°。另外,添加氯化镧后疏水膜的盐雾时间延长至109.0 h,耐蚀性大幅提高。     

基于压迫感分析的城市高架桥美学设计研究

为解决城市高架桥对其地面道路及周边地块产生的压迫感这一问题,并且指导城市高架桥的设计和规划,使之在满足交通功能和用地要求的同时兼顾美学的考虑,研究根据压迫感主要来源为建筑对视野限制的推论,分析了压迫感的主要影响因素为建筑在视野中形成的视角,讨论了现有立体角理论模型的适用性,并且结合城市高架桥视角的特点,将立体角理论模型简化为平面视角理论模型以增强其适用性。建立了桥梁的结构尺寸与影响点的视角的关系式,以压迫感接受率表征压迫感的大小,再根据调查统计数据拟合,确定视角与压迫感接受率的关系曲线,从而得到桥梁的结构尺寸与影响点压迫感接受率的关系式。在规划和设计时,可根据该公式合理确定桥梁下地面道路的红线宽度或两侧地块的退红净距。     

基于火箭遥测的地面站接收信号情况预估方法

火箭尾焰造成的信号衰减是地面测量点位选择重点考虑的问题,通常采用传统β角确定火箭尾焰对遥测地面站接收信号的影响程度。针对新型固体火箭发射中β角分析法对遥测地面站接收信号情况预测不准确的问题,文中在分析影响遥测地面站信号接收因素的基础上,提出了一种采用信号衰减方向性预估遥测地面站接收信号情况的模型。通过分析火箭遥测实测飞行姿态、位置以及地面遥测设备实际跟踪信号情况确定了模型参数,并通过实例计算证明了该方法优的优越性。     

任意角带式输送机转弯装置应用研究

煤炭运输线路出现变向转弯时，通过多台传统带式输送机搭接实现输送，存在设备投资大、运输系统复杂、人员需求多等问题。介绍了任意角带式输送机转弯装置的工作原理、结构组成和特点，任意角带式输送机转弯装置由转向模块、改向模块、受料模块及其他辅助装置组成，当巷道转弯角度变化后，仅需要调节转向和改向滚筒即可实现带式输送机转向。该设备结构新颖、承载力大、运转安全可靠，可实现对带式输送机防逆转、制动，克服了转向运行时胶带的滑移和受力不均等问题，实现了减人提效，同时，安装时不需要开掘机电设备硐室，减少了巷道工程量，具有广阔的推广前景。     

Short‐Term Morphology Relaxation of Thermoplastic Polyurethane Elastomers after Fast Strain Steps

Strain steps are applied to elastomers in a pneumatic relaxometer and monitored by small‐angle X‐ray scattering (SAXS). The relaxometer provides a rise time of 13 ms for strain pulses of step height Δε = ±1 in strain. The basic character of the 2D SAXS frames is examined and corresponding invariants Q(t) are analyzed. Three thermoplastic polyurethanes (TPU) of hardness 85 Shore A with different soft segments are studied both unannealed and annealed. The first response of all materials is a fast morphology conversion which finishes within t_mc =250 ms. Because it has been untraceable, it is characterized by a settling stroke Q(t_mc) ? Q(0). The second response is a slow morphology adjustment process which complies with logarithmic relaxation. It is characterized by a relaxation rate D_Q = Q(10 t)/Q(t) ? 1. Comparison indicates that the nanoscopic morphology relaxation processes appear to have little direct relation to the macroscopic stress relaxation curves. The materials differ with respect to hard‐domain morphology stability and morphology recovery. Most unstable is the morphology of the annealed polyether‐based material. It forms nanofibrillary entities when strained.     

Investigating the effect of silver nanorods embedded in polydimethylsiloxane matrix using nanoindentation and its use for flexible electronics

The stretchable electrodes with excellent flexibility, electrical conductivity, and mechanical durability are the most fundamental components in the emerging and exciting field of flexible electronics. This article proposes a method for fabrication of such a stretchable electrode by embedding silver nanorods (AgNRs) into a polydimethylsiloxane (PDMS) matrix that is grown by a unique glancing angle deposition technique. The surface, mechanical, and electrical properties of PDMS are significantly changed after embedding the AgNRs in it. The results show that surface roughness and polarity increase after AgNRs are embedded in the PDMS matrix. Elastic modulus (E) and hardness (H) decrease with an increase in the indentation load as a result of the indentation depth effect. Due to strong interfacial adhesion of AgNRs embedded in the PDMS matrix, the E and H of nanocomposite are increased by 167.6 and 93.3% compared with PDMS film, respectively. Furthermore, the AgNRs-PDMS film has an electrical resistivity value in the order of 10⁻⁷ Ωm. It remains conductive during various mechanical strains such as bending, twisting, and stretching, which is demonstrated using a light-emitting diode circuit. Simultaneously, the antimicrobial activity of silver could make it a promising candidate for wearable electronics.